Ammonium Acetate as a very Simple and Efficient Cocatalyst for Manganese Porphyrin-catalysed Oxygenation of Hydrocarbons by Hydrogen Peroxide

DOI: 10.1039/c39940001035

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1035 - 1036 (1994)

Update date:2022-08-17

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Authors:

Thellend, Annie

Battioni, Pierrette

Mansuy, Daniel

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Article abstract of DOI:10.1039/c39940001035

A one-phase system using chloromanganese(III) catalyst and ammonium acetate cocatalyst epoxidised alkenes by H2O2 with complete conversion in excellent yield and hydroxylated alkanes with yields of 45-87percent; for most reactions this system gave better results than a previously described analogous system using imidazole cocatalyst.

Full text of DOI:10.1039/c39940001035

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