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Dalton Transactions
Page 7 of 9
DOI: 10.1039/C6DT04262G
Journal Name
ARTICLE
Lorenzo-Luis, A. Romerosa and J. M. Padrón, Bioorg. Med.
Chem. Lett., 2011, 21, 4568.
and NPTA. The stabilization of reaction intermediates by
interaction among all the ligands with water is therefore an
important aspect of the reaction mechanism that must be
studied as it could be an important factor also in known
catalysed isomerization processes in water, some of them
faster than presented.22 Theoretical and experimental works
are in progress to determine the mechanism of the catalytic
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9
F. Scalambra, M. Serrano-Ruiz, S. Nahim-Granados and A.
Romerosa, Eur. J. Inorg. Chem., 2016, 10, 1528.
T. Campos-Malpartida, F. Joó, M. Fekete, Á. Kathó, A.
Romerosa, M. Saoud and W. Wojtków, J. Organomet. Chem.,
2008, 693, 468.
10 (a) S. Bolaño, L. Gonsalvi, F. Zanobini, F. Vizza, V. Bertolasi, A.
Romerosa and M. Peruzzini, J. Mol. Catal. A: Chem., 2004,
224, 61; (b) M. Saoud, A. Romerosa, and M. Peruzzini,
Organometallics, 2000, 19, 4005.
isomerization process mediated by
substrate molecules participate in it.
1 and how water and
11 B. González, P. Lorenzo-Luis, M. Serrano-Ruiz, M. É Papp, M.
Fekete, K. Csépke, K. Osz, Á. Kathó, F. Joó and A. Romerosa,
J. of Mol. Catal. A: Chem., 2010, 326, 15.
12 M. Serrano-Ruiz, M.; P. Lorenzo-Luis, A. Romerosa and A.
Mena-Cruz, Dalton Trans., 2013, 42, 7622.
Thanks are given to the European Commission FEDER program 13 C. A. Mebi, R. P. Nair, R. P. and B. J. Frost, Organometallics
Acknowledgements
2007, 26, 429.
for co-financing the project CTQ2015-67384-R (MINECO).
Thanks are also given to Junta de Andalucía PAI-research group
FQM-317 and COST Action CM1302 (WG1, WG2). F. S. is
grateful to the University of Almeria for a predoctoral grant.
We are very grateful to Mareck Jura and Leonardo Bernasconi
(Appelton-Rutherford Laboratory, Oxfordshire, U. K.) for
facilitating the X-ray determination, suggestions, discussion
and checking the paper.
14 L. Bellarosa, J. Díez, J. Gimeno, A. Lledós, F. J. Suárez, G.
Ujaque and C. Vicent, C. Chem. Eur. J., 2012, 18, 7749.
15 (a) A. Romerosa, T. Campos-Malpartida, C. Lidrissi, M. Saoud,
M. Serrano-Ruiz, M. Peruzzini, J. A. Garrido-Cárdenas and F.
García-Maroto, Inorg. Chem., 2006, 45, 1289; (b) D. N.
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16 P. Crochet and V. Cadierno, Dalton Trans., 2014, 43, 12447.
17 See for example: S. S. Bosquain, A. Dorcier, P. J. Dyson, M.
Erlandsson, L. Gonsalvi, G. Laurenczy and M. Peruzzini, Appl.
Organomet. Chem., 2007, 21, 947. (b) A. Rossin, L. Gonsalvi,
A. D. Phillips, O. Maresca, A. Lledos and M. Peruzzini,
Organometallics, 2007, 26, 3289. Some reviews covering the
chemistry of PTA and its derivatives: (c) A. D. Phillips, L.
Gonsalvi, A. Romerosa, F. Vizza and M. Peruzzini, Coord.
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A. Mena-Cruz, M. Serrano-Ruiz, P. Lorenzo-Luis, A.
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