Self-catalysis in arene exchange reactions of (arene)tricarbonylchromium complexes

DOI: 10.1021/om00080a029

Source and publish data:

Organometallics p. 325 - 327 (1984)

Update date:2022-08-17

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Authors:

Traylor Traylor

Stewart, Kevin

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Article abstract of DOI:10.1021/om00080a029

The replacement of p-xylene from its tricarbonylchromium complex by benzene is catalyzed by (hexamethylbenzene)tricarbonylchromium without the replacement of hexamethylbenzene. This and other observations suggest that the bound carbonyl group acts as a nucleophilic catalyst in arene exchange.

Full text of DOI:10.1021/om00080a029

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