Journal of the American Chemical Society p. 2387 - 2391 (1980)
Update date:2022-08-12
Topics:
Willey, John F.
Taylor, James W.
Techniques for the measurement of bromine leaving group kinetic isotope effects (KIE) are described.Experimental values at 20 deg C for the solvolysis of tert-butyl bromide (0.045M) in methanol with 0.3M 2,6-lutidine and for the reaction of n-butyl bromide (0.047M) with thiophenoxide anion (0.052M) in 0.025M lithium methoxide/methanol solvent are 1.00310 (+/-0.00004) and 1.00169 (+/-0.00003), respectively.The natural logarithm of the KIE was found to vary lineary with 1/T from 0 to 40 deg C for tert-butyl bromide, slope=0.472 (+/-0.080) deg-1, and from -10 to 40 deg C for n-butyl bromide, slope=0.531 (+/-0.29) deg-1.The significance of the KIE temperature dependencies is discussed.
View More
Contact:732.938.2777
Address:5012 Industrial Road Farmingdale, NJ 07727
Nanjing Xi Ze Biological Technology Co., Ltd
Contact:86-025-66023220
Address:Address: Nanjin Qixia District Maigaoqiao R & D base in Pioneer Park Chun Yin Road 18-A928
shanghai meicheng chemical co .,ltd(expird)
Contact:+86-21-50677091
Address:Room 302, Building 7, No.1000, Jinhai Road
Wuhan Yitongtai Science and Technology Co.,Ltd.
Contact:+86-27-88933550
Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
SHANGHAI SYSTEAM BIOCHEM CO., LTD
website:http://www.systeambc.com
Contact:86-021-58380978
Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
Doi:10.1021/acs.inorgchem.8b01733
(2018)Doi:10.1016/S0022-328X(00)98078-1
(1977)Doi:10.1002/anie.201710186
(2017)Doi:10.1002/chem.201003376
(2011)Doi:10.1016/j.tetlet.2020.151657
(2020)Doi:10.1155/2017/1509129
(2017)
