Rate of deprotonation of a simple ketone by lithium diisopropylamide

DOI: 10.1016/S0040-4039(98)00015-X

Source and publish data:

Tetrahedron Letters p. 1661 - 1664 (1998)

Update date:2022-08-11

Topics:

Authors:

Majewski, Marek

Nowak, Pawel

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Article abstract of DOI:10.1016/S0040-4039(98)00015-X

Rate studies on deprotonation of a simple ketone (R-2,2,6- trimethylcyclohexanone) with lithium diisopropylamide are described. The data are consistent with the reaction being first order in ketone and half order in the base, corresponding to the rate equation: v = k[ketone][LDA](1/2).

Full text of DOI:10.1016/S0040-4039(98)00015-X

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