Bulletin of the Chemical Society of Japan p. 2594 - 2598 (1989)
Update date:2022-08-16
Topics:
Kozuka, Seizi
Nitta, Takemi
Tamura, Shoji
Tagaki, Waichiro
Kinetic and stereochemical studies have been conducted on the reaction of (arylthio)trimethylgermanes with 1-aryl-1-bromoethanes.The reaction has been found to obey a first-order kinetic equation.The rates of the reaction of the substituted arylethanes were well-correlated with ?+ constants.Optically active 1-bromo-1-phenylethane gave racemic phenyl 1-phenylethyl sulfide by the reaction with trimethyl(phenylthio)germane.An SNL ionization of 1-aryl-1-bromoethanes has been suggested as the reaction mechanism.
View More
Yantai Jiacheng Chemical Technology Co., Ltd.
Contact:535-6303697,18663837927
Address:70# Qunying Road, Fushan District,Yantai, China
Shanghai Rainbow Chemistry Co., Ltd.
Contact:+86-21-64968086-5815/5812
Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
xi'an taima biological engineering co., ltd.
Contact:+8615619038117
Address:6 No,keji road xi'an city of china
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Contact:+86-(0)21-3770 9035
Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Doi:10.1248/cpb.47.983
(1999)Doi:10.1021/acs.orglett.9b03400
(2019)Doi:10.1007/BF03246033
(2010)Doi:10.1071/CH16540
(2017)Doi:10.1002/ejoc.201300414
(2013)Doi:10.1016/j.jfluchem.2015.11.002
(2016)
