Asymmetric catalytic cyanosilylation of aldehydes using a chiral binaphthol-titanium complex

DOI: 10.1016/S0040-4039(97)01432-9

Source and publish data:

Tetrahedron Letters p. 6229 - 6232 (1997)

Update date:2022-08-18

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Authors:

Mori, Maki

Imma, Hironori

Nakai, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(97)01432-9

The asymmetric catalytic cyanosilylation of aliphatic aldehydes with Me₃SiCN using (R)-BINOL-Ti(O-i-Pr)₂ as an asymmetric precatalyst is shown to proceed smoothly in dichloromethane to afford the cyanohydrins in relatively high enantioselectivity (up to 75% ee).

Full text of DOI:10.1016/S0040-4039(97)01432-9

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