Chemistry Letters p. 547 - 550 (1985)
Update date:2022-08-11
Topics:
Shikada, Tsutomu
Yagita, Hiroshi
Fujimoto, Kaoru
Tominaga, Hiro-o
A molybdenum-active carbon catalyst was found to catalyze the vapor phase carbonylation of methyl acetate and related compounds under pressurized conditions in the presence of methyl iodide promoter.Acetic anhydride was formed from methyl acetate with an yield of 15percent and a selectivity of 83percent at 250 deg C and 45 atm.The molybdenum-active carbon catalyst was active also for the carbonylation of methanol and dimethyl ether to form methyl acetate.
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