Chemistry Letters p. 1849 - 1852 (1983)
Update date:2022-08-11
Topics:
Morikawa, Yutaka
Wang, Fey-long
Moro-oka, Yoshihiko
Ikawa, Tsuneo
The catalytic activities of Ti ion exchanged forms of layered silicate minerals are completely different by the ionic valencies.Methanol was dehydrated to dimethyl ether and hydrocarbons over Ti(IV) forms of the minerals, whereas dehydrogenated to methyl formate and methylal over Ti(III) forms of the minerals.It is of particular interest that acetone is formed from methanol over Ti(III) form of fluoro tetrasilicic mica (Ti(III)-TSM).
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