Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 609 - 616 (1984)
Update date:2022-08-11
Topics:
Baulch, Donald L.
Campbell, Ian M.
Chappel, Jonathan M.
The principal products from the surface-initiated reactions in flowing mixtures of H2O2, NO2,N2 and RH, where RH=ethane, propane, n-butane and n-pentane, have been identified as the nitroalkane, alkyl nitrite and alkyl nitrate.The product yields have been measured; in the case of propane the variation of the yields with total gas pressure has also been studied.Values have been obtained for the relative rates of primary and secondary H-atom abstraction from each alkane by OH and for the rate-constant ratios k3/k4 and k5/k6 at 298 K:
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