Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 617 - 628 (1984)
Update date:2022-08-16
Topics:
Baulch, Donald L.
Campbell, Ian M.
Chappel, Jonathan M.
The effects of oxygen on the product distribution from the surface-initiated reactions in flowing mixtures of H2O2, NO2, N2 and RH, where RH=ethane, propane, n-butane and n-pentane, at 298 K have been studied.In the absence of O2, the principal products are the corresponding nitroalkane, alkyl nitrite and alkyl nitrate.In the presence of sufficiently large concentrations of O2, the predominant product is the alkyl nitrate and the only other products of significance, in some cases, are the corresponding carbonyl compounds.The variation of the product yields with
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