Journal of the Chemical Society. Chemical communications p. 1490 - 1491 (1984)
Update date:2022-08-11
Topics:
Yamamoto, Koji
Fukushima, Hitoshi
Nakazaki, Masao
Oxidative coupling of 9-phenanthrol (1) with a (-)-(R)-1,2-diphenylethylamine-copper(II) complex yielded (-)-(S)-10,10'-dihydroxy-9,9'-biphenanthryl (2) (98percent optical purity); the chiral aluminium hydride reagent modified by (2) was found to exhibit enantioface selectivity towards a variety of prochiral carbonyl compounds.
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