Applied Catalysis A: General p. 123 - 130 (2016)
Update date:2022-08-29
Topics:
Li, Rui
Shahbazi, Abolghasem
Wang, Lijun
Zhang, Bo
Hung, Albert M.
Dayton, David C.
Graphite encapsulated molybdenum carbides (Mo2C@C) were synthesized via the hydrothermal carbonization of a solution of glucose and ammonium molybdate followed by temperature programmed reduction. Characterization and structural analyses revealed that the synthesized Mo2C@C nanoparticles had a molybdenum core/carbon shell structure with a particle size ranging from 50 nm to 100 nm and a core size range of 5–45 nm. The catalytic performance of the graphite encapsulated molybdenum carbides was evaluated on conversion of guaiacol to phenolic compounds in methanol. At 340 °C under 2.8 MPa hydrogen pressure, a 76.3% guaiacol conversion was obtained with selectivities of 68.6% for phenol and 93.5% for phenolic compounds. Thus, Mo2C@C showed high selectivity for phenolic compounds in methanol.
View MoreZibo Fuxi'er Chemical Co.,Ltd (Shanxian Fuxi'er Chemical Co.,Ltd)
Contact:+86-533-2091422
Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Tianjin Chemsyntech Chemical Co., Ltd
Contact:+86-22-60872258
Address:Haitai green industry base in Tianjin, K1,5-601
Shantou Baokang Pharmaceutical Co., Ltd.
Contact:+86-754-88873487
Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530-8001
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Contact:+1-284-4950244
Address:Box 3069, Road Town, Tortola, British Virgin Islands
Doi:10.1039/C8DT03164A
(2018)Doi:10.1016/j.cclet.2021.07.053
(2022)Doi:10.1002/oms.1210220209
(1987)Doi:10.1002/chem.200600869
(2007)Doi:10.1039/c5tc00512d
(2015)Doi:10.1039/b102923c
(2001)