Autocatalysis and Free Radical Mechanism in a Ruthenium Cluster Catalysed Hydrogen Transfer Reaction

DOI: 10.1039/c39900001506

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1506 - 1508 (1990)

Update date:2022-08-30

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Authors:

Bhaduri, Sumit

Mukesh, Doble

Sharma, Krishna

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Article abstract of DOI:10.1039/c39900001506

The mechanisms of the <(Ph3P)2N> 1 catalysed disproportionation and transfer-hydrogenation of cyclohex-2-en-1-one have been shown to involve free radicals; in the latter reaction 1 is converted to the other carbonyl species via autocatalysis.

Full text of DOI:10.1039/c39900001506

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