Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 226 - 232 (1990)
Update date:2022-08-11
Topics:
Petrov, L. V.
Drozdova, T. I.
Lyuta, L. Ya.
Solyanikov, V. M.
Ketones and aldehydes accelerate decomposition of hydroperoxides in acetonitrile solution in the presence of strong acids.An explanation of the effect, due to the formation of semiperketals (semiperacetals) which undergo rapid acid-catalytic decomposition, is proposed.The macrostage character of the reaction of acid-catalyzed decomposition of cyclohexyl hydroperoxide was demonstrated for the first time.The initially slow decomposition takes place homolytically and yields the product cyclohexanone, which accelerates decomposition.
View MoreNINGBO PANGS CHEM INT’L CO., LTD.
Contact:+86-0574-27666801
Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
shijiazhuang shuanglian chemical industry co.,ltd
Contact:0311-82190302
Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway,Shijiazhuang City
SHENYANG COMEBOARD TECHNOLOGY CO., LTD
Contact:+86-24-25724626
Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Zhejiang Allied Chemical Co.,Ltd
Contact:18967038207
Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Contact:86-311-67265101
Address:203 Lianmeng Road, Qiaoxi District
Doi:10.1016/j.mcat.2020.111239
(2020)Doi:10.1039/d0nj04962j
(2021)Doi:10.1002/jccs.200000129
(2000)Doi:10.1002/jhet.3959
(2020)Doi:10.1016/0040-4020(94)00979-5
(1995)Doi:10.1016/j.catcom.2010.04.009
(2010)