Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 226 - 232 (1990)
Update date:2022-08-11
Topics:
Petrov, L. V.
Drozdova, T. I.
Lyuta, L. Ya.
Solyanikov, V. M.
Ketones and aldehydes accelerate decomposition of hydroperoxides in acetonitrile solution in the presence of strong acids.An explanation of the effect, due to the formation of semiperketals (semiperacetals) which undergo rapid acid-catalytic decomposition, is proposed.The macrostage character of the reaction of acid-catalyzed decomposition of cyclohexyl hydroperoxide was demonstrated for the first time.The initially slow decomposition takes place homolytically and yields the product cyclohexanone, which accelerates decomposition.
View More
Yueyang Hudex Pharmaceuticals Ltd.
Contact:0730-8748800
Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone
Shuanghe Bio-Technology Limited(expird)
Contact:+86-571-61710758,18968016640
Address:Jinqiao north road 916# Fuyang
Anhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Contact:+86-10-59484199
Address:No.58-A1026 Liangguan Street
Contact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Doi:10.1016/j.mcat.2020.111239
(2020)Doi:10.1039/d0nj04962j
(2021)Doi:10.1002/jccs.200000129
(2000)Doi:10.1002/jhet.3959
(2020)Doi:10.1016/0040-4020(94)00979-5
(1995)Doi:10.1016/j.catcom.2010.04.009
(2010)
