Organic Letters p. 1643 - 1645 (2002)
Update date:2022-08-29
Topics:
Mikami, Koichi
Yusa, Yukinori
Korenaga, Toshinobu
Matrix presented 3,3′-Dimethyl-2,2′-diamino-1,1′-binaphthyl (DM-DABN) is designed as a "chiral poison" (deactivator) for complete enantiomer resolution of racemic BINAP-Ru(II) catalysts in a highly enantioselective hydrogenation of β-keto ester and kinetic resolution of racemic 2-cyclohexen-1-ol.
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