TRIHYDRIDORUTHENIUM(IV) COMPLEXES: PREPARATION AND PHOTO-INDUCED H/D EXCHANGE REACTION

DOI: 10.1016/0022-328X(86)80551-4

Source and publish data:

Journal of Organometallic Chemistry p. C45 - C47 (1986)

Update date:2022-08-11

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Authors:

Suzuki, Hiroharu

Lee, Dong Hwan

Oshima, Noriaki

Moro-Oka, Yoshihiko

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Article abstract of DOI:10.1016/0022-328X(86)80551-4

The trihydrides (η⁵-C5Me5)RuH3)(PR3)(PR3 = PMe3, PEt3, Pipr3, PCy3, PPh2Me, and PPh3) (2) are formed in the reaction of paramagnetic (η⁵-C5Me5)RuCl2(PR3) (1) with NaBH4 in ethanol.The reaction of 1 with NaBH4 in THF yields intermedia

Full text of DOI:10.1016/0022-328X(86)80551-4

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