Chemical and Pharmaceutical Bulletin p. 17 - 21 (1998)
Update date:2022-08-29
Topics:
Horikawa, Tamaki
Norimine, Yoshihiko
Tanaka, Masakazu
Sakai, Kiyoshi
Suemune, Hiroshi
Optically active 5-cyclooctene-1,2-diol derivatives prepared by an enzymatic procedure have been converted into bicyclo[3.3.0]octane derivatives by transannular reaction with complete inversion of the stereogenic center linked to the leaving group. Formal synthesis of (+)-iridomyrmecin has been achieved starting from (S,S)-5-cyclooctene-1,2-diol by using this process.
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(1954)