Advanced Synthesis and Catalysis p. 5400 - 5405 (2019)
Update date:2022-08-11
Topics:
Zhu, You-Quan
Hui, Li-Wen
Niu, Yun-Xia
Lv, Lin-Ge
Zhu, Kun
Under rhodium(III) catalysis, substituted N-methoxycycloalkene-1-carboxamides successfully reacted with aryl boronic acid pinacol esters to provide 3,4-cycloalkaquinolin-2(1H)-ones via direct functionalization of the β-alkenyl C?H bond and form C?C/C?N bond in one pot. The gram-scale synthesis of the title compound demonstrated the great synthetic utility of this methodology. (Figure presented.).
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