Journal of Fluorine Chemistry p. 319 - 326 (1988)
Update date:2022-08-11
Topics:
Conte, L.
Gambaretto, G. P.
Napoli, M.
Gervasutti, C.
The hydrohalo-olefins cis and trans CHCl=CHCl, CHCl=CCl2, CHCl=CH-CH2Cl and CH2=CCl-CH2Cl have been fluorinated with elemental fluorine to give good yields of hydrohalofluoroalkanes.The best operational conditions for F2 addition to the double bond rather than hydrogen and/or chlorine atom substitution, dimerization and oligomerization of radical intermediates have been studied.Pleriminary studies on the reaction of Freon 12 and Freon 22 towards elemental fluorine have also been carried out.
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