Novel stereoselective synthesis of glycosyl-1-O-acyl esters via peracetylglycosyl phosphorothioates, -selenoates and -dithioates as glycosyl donors

Article abstract of DOI:10.1055/s-1996-4311

An efficient and highly β-stereoselective synthesis of glycosyl 1-O-acyl esters based on reaction of easily accessible glycosylthio-, seleno- and dithiophosphates 1-6 as glycosyl donors with carboxylic acids 7-13 as glycosyl acceptors in the presence of silver salts as activators is described.