Tetrahedron p. 4235 - 4242 (1989)
Update date:2022-08-11
Topics:
Houen, G.
Larsen, C.
Larsson, L.-I.
Pyrroloquinoline quinone (PQQ) was found to oxidize the polyamines spermine and spermidine in stoichiometric amounts with diaminopropane as the main product identified by reversed phase high performance liquid chromatography and mass spectroscopy of the reaction products.Putrescine was oxidized much slower than the polyamines and cetyl-trimethyl-ammonium bromide did not promote oxidation.A model for the PQQ oxidation of polyamines is suggested to account for these observations.
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(1981)
