Solvent-free synthesis of decyl D-glycopyranosides under focused microwave irradiation

Article abstract of DOI:10.1080/07328309708006533

A three step microwave assisted solvent-free synthesis of decyl D-glucopyranoside with 1-decanol was established for D-glucose and extended to D-galactose, D-mannose and N-troc-D-glucosamine with 70% average overall yield for the three steps (peracetylation, glycosylation and saponification). Rate enhancements and reduction of the reaction time were observed for the two last steps carried out under microwave irradiation when compared to conventional heating in the same conditions.

Full text of DOI:10.1080/07328309708006533

This article was downloaded by: [University of Arizona]
On: 13 May 2013, At: 00:38
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered
office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Journal of Carbohydrate Chemistry
Publication details, including instructions for authors and
subscription information:
http://www.tandfonline.com/loi/lcar20
Solvent-Free Synthesis of Decyl D-
Glycopyranosides Under Focused
Microwave Irradiation
C. Limousin a , J. Cléophax a , A. Petit b , A. Loupy b & G. Lukacs a
a Institut de Chimie des Substances Naturelles, C.N.R.S., Avenue de
la Terrasse, 91198 Gif-sur-Yvette, France
b Laboratoire des Réactions Sélectives sur Supports, associé au
C.N.R.S., ICMO, Université Paris-Sud bat. 410, 91405, Orsay, France
Published online: 19 Aug 2006.
To cite this article: C. Limousin , J. Cléophax , A. Petit , A. Loupy & G. Lukacs (1997): Solvent-Free
Synthesis of Decyl D-Glycopyranosides Under Focused Microwave Irradiation, Journal of Carbohydrate
Chemistry, 16:3, 327-342
To link to this article: http://dx.doi.org/10.1080/07328309708006533
PLEASE SCROLL DOWN FOR ARTICLE
Full terms and conditions of use: http://www.tandfonline.com/page/terms-and-conditions
This article may be used for research, teaching, and private study purposes. Any
substantial or systematic reproduction, redistribution, reselling, loan, sub-licensing,
systematic supply, or distribution in any form to anyone is expressly forbidden.
The publisher does not give any warranty express or implied or make any representation
that the contents will be complete or accurate or up to date. The accuracy of any
instructions, formulae, and drug doses should be independently verified with primary
sources. The publisher shall not be liable for any loss, actions, claims, proceedings,
demand, or costs or damages whatsoever or howsoever caused arising directly or
indirectly in connection with or arising out of the use of this material.