(2?+4?) PHOTOCYCLOADDITION OF 1,2-DIARYLCYCLOPROPANES TO 9,10-DICYANOANTHRACENE VIA GEMINATE RADICAL ION PAIR

DOI: 10.1016/S0040-4039(00)85282-X

Source and publish data:

Tetrahedron Letters p. 5619 - 5620 (1986)

Update date:2022-08-16

Topics:

Authors:

Ichinose, Nobuyuki

Mizuno, Kazuhiko

Hiromoto, Ziro

Otsuji, Yoshio

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Article abstract of DOI:10.1016/S0040-4039(00)85282-X

Irradiation of a degassed acetonitrile solution containing 9,10-dicyanoanthracene (DCA) and 1,2-diarylcyclopropanes gave (2?+4?) photocycloadducts in good yields.The geminate radical ion pairs betwen DCA and the cyclopropanes are involved as key intermediates in this photoreaction.

Full text of DOI:10.1016/S0040-4039(00)85282-X

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