Journal of Organometallic Chemistry p. 159 - 172 (1980)
Update date:2022-08-11
Topics:
Koning, A. J. De
Boersma, J.
Kerk, G. J. M. van der
The synthesis and characterization of 1,4-dihydro-1-pyridylzinc and -magnesium complexes are described.Zinc hydride and magnesium hydride dissolve in and react with pyridine, and the reaction has been studied in detail in the case of zinc hydride.Evaporation of the solvent after 1-2 hours at 0 deg C yielded a product containing pyridine, a 1,4-dihydropyridyl moiety and zinc hydrogen bonds, and two alternative structures are proposed for this complex.When the reaction was carried on for a long period, a yellow precipitate began to separate after about 40 hours, andreaction was complete after 7 days.The yellow product was identified as the pyridine complex of bis(1,4-dihydro-1-pyridyl)zinc.The corresponding magnesium complex was obtained from the reaction between magnesium hydride and pyridine for 50 hours at room temperature.
Suzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Zhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Contact:+86-21-54391580
Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
JiYi Chemical (Beijing) Co., Ltd.
Contact:+86-10-89385733
Address:Shilou Town of Fangshan District， Beijing
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Doi:10.1021/jf052102k
(2006)Doi:10.1021/acscatal.5b02613
(2016)Doi:10.1248/yakushi1947.84.8_699
(1964)Doi:10.1016/j.jallcom.2016.02.078
(2016)Doi:10.1021/ic50226a051
(1981)Doi:10.1002/chir.20834
(2011)
