Monatshefte fur Chemie p. 681 - 686 (1995)
Update date:2022-08-11
Topics:
Holba, V.
Sumichrast, R.
Oxidations of hexan-1-ol, hexan-2-ol, hexan-3-ol, heptan-1-ol, heptan-2-ol, octan-1-ol, and octan-2-ol with tetra-1-butylammonium permanganate, dissolved in the same alcohols, proceed partly autocatalytically.The rate constants of both catalytic and non-catalytic reactions have been evaluated.Colloidal manganese dioxide, one of the reaction products, has been identified as the catalyst. - Keywords: Autocatalysis; Kinetic parameters; Colloidal MnO2
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