Journal of Organometallic Chemistry p. 285 - 292 (1985)
Update date:2022-08-11
Topics:
Ang, H. G.
Lau, P. T.
The reactions of (o-diphenylphosphinobenzyl)dimethylsilane with manganese and rhenium carbonyl afford o-(C6H5)2PC6H4CH2Si(CH3)2M(CO)4 (M=Mn, Re), in which the ligand behaves as a chelate.Similar reactions occur with ?-cyclopentadienemolybdenum tricarbonyl dimer to give o-(C6H5)2PC6H4CH2Si(CH3)2Mo(?-C5H5)(CO)2.However, photolysis of a mixture of the ligand with manganese carbonyl yielded o-(C6H5)2PC6H4CH2Si(H)(CH3)2Mn2(CO)9.
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