Enantioselective Synthesis of Homoallylic Amines by Addition of Allylmetal Reagents to Imines Derived from (S)-Valine Esters

DOI: 10.1021/jo00104a037

Source and publish data:

Journal of Organic Chemistry p. 7766 - 7773 (1994)

Update date:2022-08-30

Topics:

Authors:

Basile, Tiziana

Bocoum, Allaye

Savoia, Diego

Umani-Ronchi, Achille

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Article abstract of DOI:10.1021/jo00104a037

Grignard and Barbier procedures have been applied to the addition of allylmethal (Zn, Cu, Pb, Bi, Al, In) species to imines derived from (S)-valine esters, principally the methyl ester.The Zn-mediated, CeCl3- or SnCl2-catalyzed "Barbier" reactions of the

Full text of DOI:10.1021/jo00104a037

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