Bulletin of the Chemical Society of Japan p. 1729 - 1734 (1990)
Update date:2022-08-11
Topics:
Kato, Nobuo
Wu, Xue
Tanaka, Shinya
Takeshita, Hitoshi
An improved eight-membered ring closure by means of a Lewis-acid-catalyzed ene reaction was applied to the synthesis of cycloaraneosene and its congener, "hydroxycycloaraneosene".Comparisons of the NMR spectral data of the synthetic and natural compounds established that the natural product possesses an 8β-hydroxy structure, not the originally proposed 9α-hydroxy one.
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Doi:10.1016/0031-9422(90)80139-8
(1990)Doi:10.1021/jacs.8b03998
(2018)Doi:10.1016/j.ica.2017.07.004
(2017)Doi:10.1002/jccs.200500071
(2005)Doi:10.1021/ac200755c
(2011)Doi:10.1007/s12272-012-0308-3
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