Journal of Organometallic Chemistry p. 361 - 366 (1981)
Update date:2022-08-30
Topics:
Strohmeier, Walter
Marcec, Radovan
Graser, Barbara
Hydroformylation of 1-hexene in the gas phase has been carried out at 120 deg C and 3 to 9 bar pressure with solution of the homogeneous catalyst RhHCO(PPh3)3 in molten PPh3, which was dispersed into the pores of the carrier Chromosorb.Above a critical gas flow no condensation of product heptanal (b.p. 155 deg C) was observed.Conversion of 1-hexene to heptanal is a function of reactor length, gas flow and pressure of CO/H2.The ratio of n/iso-aldehyde can be adjusted to 45/1 and is much higher than in liquid bulk hydroformylation.
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