Low pressure catalytic hydroformylation of 1-hexene by the carbonylhydrido-tris(triphenylphosphine)rhodium(I), RhH(CO)(PPh3)3, in association with phosphinomethylzirconium complexes

DOI: 10.1016/0022-328X(87)87117-6

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C12 (1987)

Update date:2022-08-11

Topics:

Authors:

Choukroun, R.

Gervais, D.

Kalck, P.

Senocq, F.

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Article abstract of DOI:10.1016/0022-328X(87)87117-6

Low pressure catalytic hydroformylation of 1-hexene was performed in the presence of RhH(CO)(PPh3)3 in association with diphenylphosphinomethylzirconium complexes such as Cp2Zr(CH2PPh2)2 and 2O or in the presence of bis(diphenylphosphine)butane.An isolated rhodium-zirconium complex, formulated as , was found to be catalytically active.

Full text of DOI:10.1016/0022-328X(87)87117-6

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