
Tetrahedron Letters p. 6119 - 6122 (1998)
Update date:2022-08-23
Topics:
Soderquist, John A.
Medina, Jesus R.
Huertas, Ramon
Exhibiting a broad spectrum of hydroboration reactivities, seven (7) new silylamine-borane complexes (1) were efficiently prepared from diborane and the corresponding silylated amines (2). Most are crystalline solids which are air-stable, concentrated borane sources. All provide convenient alternatives to other hydroborating agents, 2 undergoing complete hydrolysis to volatile and/or water soluble by-products upon aqueous work-up, thereby greatly facilitating the isolation of the borane-derived reaction products.
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