Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

DOI: 10.1016/0022-328X(90)80247-W

Source and publish data:

Journal of Organometallic Chemistry p. C28 - C30 (1990)

Update date:2022-08-11

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Authors:

Johnson, Brian F.G.

Lewis, Jack

Massey, Anju Deepali

Raithby, Paul R.

Wong, Wing Tak

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Article abstract of DOI:10.1016/0022-328X(90)80247-W

The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords 2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2 with an excess of dppa gives 3 (2) and 4 (3) in moderate

Full text of DOI:10.1016/0022-328X(90)80247-W

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