Synthesis of Propellanes by 'Exocyclic' Transannular Cycloaddition of Olefinic Methylenecyclopropanes

DOI: 10.1039/c39880001112

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1112 - 1113 (1988)

Update date:2022-08-11

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Authors:

Yamago, Shigeru

Nakamura, Eiichi

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Article abstract of DOI:10.1039/c39880001112

Olefinic methylenecyclopropanes undergo quantitative transannular ring closure under catalysis by Group 10 metals to give <3.3.3>propellanes, through cycloaddition of a trimethylenemethane-like intermediate.

Full text of DOI:10.1039/c39880001112

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