Synthesis of Propellanes by 'Exocyclic' Transannular Cycloaddition of Olefinic Methylenecyclopropanes

DOI: 10.1039/c39880001112

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1112 - 1113 (1988)

Update date:2022-08-11

Topics:

Authors:

Yamago, Shigeru

Nakamura, Eiichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001112

Olefinic methylenecyclopropanes undergo quantitative transannular ring closure under catalysis by Group 10 metals to give <3.3.3>propellanes, through cycloaddition of a trimethylenemethane-like intermediate.

Full text of DOI:10.1039/c39880001112

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-methylidenetetrahydro-1H,4H-3a,6a-propanopentalene

Cas No:111917-14-7

R&D Labs maybe for 111917-14-7

Zhejiang Quzhou Zhengbang Organosilicon Co.,ltd.

Contact:86-570-3375195

Address:No.17 Lingqing Road technology industry,Quzhou City,Zhejiang Province,China
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China

Relevant to this article

FURANOEREMOPHILANES AND OTHER CONSTITUENTS FROM SENECIO CANESCENS

Doi:10.1016/S0031-9422(00)97558-7
(1992)
Doi:10.1016/0020-1650(71)80050-8
(1971)
An efficient noble-metal-free supported copper catalyst for selective nitrocyclohexane hydrogenation to cyclohexanone oxime

Doi:10.1039/c6cc10267k
(2017)
Selective alkylation of pyrimidyl dianions II: Synthesis, characterization, and comparative reactivity of 3′, 5′-o-bis- tetrahydropyranyl, trimethylsilyl and tert-butyldimethylsilyl derivatives of 5-bromo-2′-deoxyuridine

Doi:10.1016/S0040-4020(01)80845-0
(1994)
An AIE-Active Conjugated Polymer with High ROS-Generation Ability and Biocompatibility for Efficient Photodynamic Therapy of Bacterial Infections

Doi:10.1002/anie.201916704
(2020)
Sodium, magnesium and zinc complexes of mono(phenolate) heteroscorpionate ligands

Doi:10.1039/b813116c
(2009)

Article Doi