Journal of the Chemical Society. Chemical communications p. 1428 - 1429 (1987)
Update date:2022-08-17
Topics:
Regen, Steven L.
Kodomari, Mitsuo
Addition of hept-1-ene to a suspension of polystyrene-bound forms of hydridocarbonyltris(triphenylphosphine)rhodium(I) and methylenetriphenylphosphorane in tetrahydrofuran, under a hydrogen/carbon monoxide atmosphere (60 deg C; 120 lb in-2), produces 2-methylheptanal (10percent), n-octanal (45percent), n-decanal (12percent), n-dodecanal (2percent), and n-tetradecanal (0.3percent) as major products.
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