An Unusual Anti-Markovnikov Hydration of Alkenes with Titanium(III) Tetrahydroborates

DOI: 10.1016/S0040-4039(00)60086-2

Source and publish data:

Tetrahedron Letters p. 171 - 174 (1993)

Update date:2022-08-18

Topics:

Authors:

Kumar, K. S. Ravi

Baskaran, S.

Chandrasekaran, S.

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Article abstract of DOI:10.1016/S0040-4039(00)60086-2

Titanium(III) tetrahydroborate formed by the reaction of titanium tetrachloride and benzyltriethylammonium borohydride (1:4) reacts with alkenes in dichloromethane (-20 deg C) very readily to yield directly the corresponding alcohols in excellent yields after a simple aqueous work up.

Full text of DOI:10.1016/S0040-4039(00)60086-2

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