New reaction of thiocarbonyl ylides. Interaction of S-alkyl-N,N-dimethylthiobenzimidium salts with activated acetylene derivatives leading to (E,E)-divinyl sulfides

DOI: 10.1007/BF02495208

Source and publish data:

Russian Chemical Bulletin p. 759 - 763 (1997)

Update date:2022-08-11

Topics:

Authors:

Magedov Magedov

Przheval'skii

Yufit Yufit

Droza Droza

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Article abstract of DOI:10.1007/BF02495208

The reaction of thiocarbonyl ylides with activated acetylene derivatives gives (E,E)-divinyl sulfides in good yields. The reaction mechanism is discussed and evidence in favor of the formation of a thiirane intermediate is presented.

Full text of DOI:10.1007/BF02495208

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