Preclusion of the "second cycle" in the osmium-catalyzed asymmetric dihydroxylation of olefins leads to a superior process

DOI: 10.1016/S0040-4039(00)89008-5

Source and publish data:

Tetrahedron Letters p. 2999 - 3002 (1990)

Update date:2022-08-22

Topics:

Authors:

Kwong, Hoi-Lun

Sorato, Carla

Ogino, Yasukazu

Chen, Hou

Sharpless, K. Barry

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Article abstract of DOI:10.1016/S0040-4039(00)89008-5

The highest enantioselectivities yet obtained in catalytic asymmetric dihydroxylations are realized using potassium hexacyanoferrate(III) [potassium ferricyanide, K₃Fe(CN)₆] as the reoxidant.

Full text of DOI:10.1016/S0040-4039(00)89008-5

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