Chemistry Letters p. 315 - 316 (1982)
Update date:2022-08-11
Topics:
Osawa, Tsutomu
Harada, Tadao
The use of a mixture of THF and carboxylic acid as the reaction medium resulted in drastic increase in the optical yield of the hydrogenation of 2-octanone to optically active 2-octanol over tartaric acid-NaBr-modified Raney nickel (TA-NaBr-MRNi).Among the carboxylic acids examined, pivalic acid gave the highest optical yield (65.6percent).
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