ASYMMETRIC TRANSFER HYDROGENATION OF KETONES CATALYZED BY PHOSPHINE-RHODIUM(I) AMD -IRIDIUM(I) COMPLEXES

DOI: 10.1016/S0022-328X(00)99002-8

Source and publish data:

Journal of Organometallic Chemistry p. 407 - 412 (1986)

Update date:2022-08-12

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Authors:

Spogliarich, R.

Kaspar, J.

Graziani, M.

Morandini, F.

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Article abstract of DOI:10.1016/S0022-328X(00)99002-8

The asymmetric hydrogen transfer from propan-2-ol to prochiral ketones is effectively catalyzed by diphosphine complexes of iridium and rhodium.The influence of the reaction conditions on the activity and selectivity of the catalysts has been investigated.

Full text of DOI:10.1016/S0022-328X(00)99002-8

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