Tetrahedron Letters p. 6903 - 6906 (1993)
Update date:2022-08-16
Topics:
Clemenceau, Denis
Cousseau, Jack
The reaction between an aldehyde R-CHO and diethyl 2-oxo-3-fluorobutan-1,4-dioate as its sodium salt EtO2C-CO-CF-CO2Et-,Na+ mainly leads in THF to (Z)-2-fluoroalkenoates R-CH=CF-CO2Et (Z/E>/=80/20), the Z-stereoselectivity depending on the bulk of the R group.Key words: 2-Fluoroalkenoates; (Z)-stereoselective synthesis.
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Doi:10.1039/P29830001373
(1983)Doi:10.1021/ja01225a600
(1945)Doi:10.1016/j.tet.2010.04.098
(2010)Doi:10.1007/BF01223548
()Doi:10.1007/s00706-018-2308-6
(2019)Doi:10.1007/BF00697104
(1993)
