Pentaco-ordinate Silicon Compounds in Synthesis: Regiospecific Allylation of Aldehydes by Use of Triethylammonium Bis(pyrocatecholato)allylsilicates

DOI: 10.1039/c39870001517

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Journal of the Chemical Society. Chemical communications p. 1517 - 1518 (1987)

Update date:2022-08-10

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Authors:

Hosomi, Akira

Kohra, Shinya

Tominaga, Yoshinori

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Article abstract of DOI:10.1039/c39870001517

The title compounds, readily prepared from allyltrimethoxysilane, pyrocatechol, and triethylamine, react with aldehydes regiospecifically and chemoselectively without catalyst under mild conditions: the allylation takes place even in protic solvents such as ethanol.

Full text of DOI:10.1039/c39870001517

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