On the Use of O-Methylmandelic Acid for the Establishment of Absolute Configuration of α-Chiral Primary Amines

DOI: 10.1021/jo00094a035

Source and publish data:

Journal of Organic Chemistry p. 4202 - 4205 (1994)

Update date:2022-08-29

Topics:

Authors:

Trost, Barry M.

Bunt, Richard C.

Pulley, Shon R.

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Article abstract of DOI:10.1021/jo00094a035

The absolute configuration of α-chiral primary amines is correlated to the relative 1H NMR shifts (upfield or downfield) observed in the diastereomeric amides formed from (S)-O-methylmandelic acid.The amides are easily formed without racemization from eit

Full text of DOI:10.1021/jo00094a035

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