Journal of Organometallic Chemistry p. C9 - C13 (1982)
Update date:2022-08-29
Topics:
Tamao, Kohei
Akita, Munetaka
Kanatani, Ryuichiro
Ishida, Neyoshi
Kumada, Makoto
A TiIII-Si active species, Cp2TiSiMe2Ph, is formed either by the reaction of Cp2TiCl2 with two equivalents of PhMe2SiLi or by the reaction of Cp2TiCl with one equivalent of PhMe2SiLi.Highly regio- and stereo-selective silyltitanation by this species has been observed with acetylenes and 1,3-dienes.
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Doi:10.3390/molecules22050833
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(2018)Doi:10.1021/ja01043a033
(1969)Doi:10.1016/S0040-4039(01)95692-8
(1973)Doi:10.1021/jacs.0c02228
(2020)Doi:10.1002/ejic.202000155
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