Angewandte Chemie - International Edition p. 1108 - 1112 (2016)
Update date:2022-08-10
Topics:
Martínez, Jose I.
Smith, Joshua J.
Hepburn, Hamish B.
Lam, Hon Wai
Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety. The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained with high enantioselectivities, where a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident. Migrate to create: Allylrhodium species from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety. The resulting allylrhodium species react with imines to give products with two new stereocenters and a Z-alkene. A chiral diene ligand leads to products with high enantioselectivities; a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident.
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