An Efficient Synthesis of Chiral Quaternary Carbon Centres with High Optical Purity Via 1,3-Chirality Transfer

DOI: 10.1039/c39870001596

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1596 - 1598 (1987)

Update date:2022-08-29

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Authors:

Ibuka, Toshiro

Tanaka, Miwa

Nishii, Shinji

Yamamoto, Yoshinori

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Article abstract of DOI:10.1039/c39870001596

An efficient synthesis of chiral quaternary carbon centres via Me2cu(CN)Li2*BF3 or RCu(CN)Li*BF3 (R<*>Me) mediated 1,3-chirality transfer of α-alkyl-γ-mesyloxy-α,β-enoates is reported.

Full text of DOI:10.1039/c39870001596

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