Synthesis p. 521 - 523 (1997)
Update date:2022-08-11
Topics:
Cai, Ming-Zhong
Song, Cai-Sheng
Huang, Xian
A silica-supported poly-γ-mercaptopropylsiloxane palladium(0) complex was prepared from poly-γ-mercaptopropylsiloxane and palladium chloride in acetone, followed by reduction with hydrazine in ethanol. The complex is a highly active and stereoselective catalyst for arylation of styrene and acrylic acid affording a variety of trans-stilbenes and substituted trans- cinnamic acids in high yields.
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