A New Approach to β-Fluoropyrroles Based on the Michael Addition of Isocyanomethylide Anions to α-Fluoroalkenyl Sulfones and Sulfoxides

DOI: 10.1246/bcsj.67.1441

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1441 - 1448 (1994)

Update date:2022-08-11

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Authors:

Uno, Hidemitsu

Sakamoto, Katsuji

Tominaga, Takashi

Ono, Noborn

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Article abstract of DOI:10.1246/bcsj.67.1441

The reactions of 2-aryl-1-fluorovinyl phenyl sulfones with carbanions derived from isocyanoacetates gave mixtures of 3-aryl-4-fluoro-2-pyrrolecarboxylates and 3-aryl-4-fluoro-4-phenylsulfonyl-2-isocyanobutanoates, simple Michael addition products, in vari

Full text of DOI:10.1246/bcsj.67.1441

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