Tetrahedron Letters p. 279 - 282 (1996)
Update date:2022-08-16
Topics:
Moss, Robert A.
Liu, Weiguo
The primary kinetic isotope effect for the 1,3-CH(D) insertion reaction of t-butylchlorocarbene-d6 ranges from 3.25 at -12 °C to 2.14 at 118 °C; tunneling is not apparent in this temperature interval.
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