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Chemistry of Materials
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results on the encapsulation of homogeneous catalysts
constitute the basic principles for the creation of a new
class of catalysts.
In conclusion, our results indicate that the self-
encapsulation procedure for heteropolyacid into the or-
dered carbon capsules demonstrates excellent perspec-
tives for the synthesis of the materials possessing high
activity and recyclability.
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ASSOCIATED CONTENT
Supporting Information. Description of synthesis proce-
dure, TEM images, TGA and elemental analysis. This materi-
al is available free of charge via the Internet at
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AUTHOR INFORMATION
Corresponding Author
* vitaly.ordomsky@univ-lille1.fr
Author Contributions
The manuscript was written through contributions of all
authors. All authors have given approval to the final version
of the manuscript.
ACKNOWLEDGMENT
[17] V.L. Sushkevich, V.V. Ordomsky, I.I. Ivanova, “Isoprene
synthesis from formaldehyde and isobutene over Keggin-type
heteropolyacids supported on silica”, Catal. Sci. Technol., 2016, 6,
6354-6364.
The authors gratefully acknowledge the Russian Science
Foundation for the financial support (Grant No. 14-23-
00094). This research is being performed within the ANR
NANO4FUT project (ANR-16-CE06-0013-01). The authors
gratefully acknowledge the support of the French National
Research Agency. The TEM facility in Lille (France) is sup-
ported by the Conseil Regional du Nord-Pas de Calais, and
the European Regional Development Fund (ERDF). The
authors acknowledge the French electron microscopy and
atom probe network, METSA.
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